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Diamond: Electronic Properties and Applications (Electronic Materials
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Table of Contents

1. Electronic and Vibrational Properties of Bulk Diamond.- 1.1 Introduction.- 1.2 Electronic Band Structure of Diamond.- 1.3 Electronic Properties Derived from the Band Structure of Diamond.- 1.4 Vibrational Properties of Diamond.- 1.5 Summary.- Acknowledgment.- References.- 2. Diamond Surface.- 2.1 Introduction.- 2.2 The Clean Surfaces: C(100), C(l 10), C(l 11).- 2.3 Impurity Stabilized Surfaces.- 2.4 Substrate Preparation and Surface Treatments.- 2.5 Surface/Interface Relevance to Electronic Devices.- 2.6 Negative Electron Affinity (NEA) Properties.- 2.7 Summary and Future Outlook.- Acknowledgments.- References.- 3. Growth of CVD Diamond for Electronic Applications.- 3.1 Introduction.- 3.2 Nucleation and Growth Processes.- 3.3 Diamond Reactor Technology.- 3.4 Gas Phase Chemistry.- 3.5 Growth of Electronic Quality Diamond.- 3.6 Summary.- References.- 4. Doped Diamond.- 4.1 Introduction.- 4.2 Natural Diamonds.- 4.3 HP/HT Synthesis.- 4.4 Ion Implantation.- 4.5 CVD Films.- 4.6 Theoretical Calculation.- 4.7 Summary.- References.- 5. Defects in Diamond.- 5.1 Introduction.- 5.2 Twins, Stacking Faults and Dislocations.- 5.3 Point Defects.- 5.4 Non-Diamond Carbon Phases.- 5.5 Other Defects.- 5.6 Summary.- Acknowledgements.- References.- 6. Free Carrier Dynamics in Diamond.- 6.1 Introduction.- 6.2. Electrical Conductivity.- 6.3 Other Transport Properties.- 6.4 Free Carrier Recombination.- 6.5 Summary.- References.- 7. Thermal Conductivity of Diamond.- 7.1 Introduction.- 7.2 Defects in Diamond.- 7.3 Theory of Themal Conduction in Semiconductors.- 7.4 Measurement Techniques.- 7.5 Results for Single Crystals.- 7.6 Results for CVD Diamond.- 7.7 Summary.- References.- 8. Electrical Contacts to Diamond.- 8.1 Introduction.- 8.2 Fabrication of Ohmic Contacts.- 8.3 Fabrication of Schottky Contacts.- 8.4 Mechanisms of Ohmic vs. Schottky Contacts Formation on Diamond.- 8.5 Summary.- Acknowledgments.- References.- 9. Electronic Device Processing.- 9.1 Introduction.- 9.2 Device Design and Substrates.- 9.3 Growth and Doping.- 9.4 Surface Preparation.- 9.5 Contact Formation.- 9.6 Dielectrics.- 9.7 Selective Deposition.- 9.8 Isolation.- 9.9 Summary.- References.- 10. Passive Diamond Electronic Devices.- 10.1 Introduction.- 10.2 Sensors and Microstructures.- 10.3 Junction Devices.- 10.4 Photoconductive and Electron-Beam Controlled Switches.- 10.5 Surface Acoustic Wave Devices.- 10.6 Electrodes.- 10.7 Energy Donversion Devices.- 10.8 Traveling Wave Devices.- 10.9 Other Devices.- 10.10 Summary.- Acknowledgments.- References.- 11. Active Diamond Electronic Devices.- 11.1 Introduction.- 11.2 Diamond Active Electronic Devices.- 11.3 Summary.- References.- Appendix Table A1. Properties of semiconductors at 293 K.

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