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Introduction to Stereochemistry


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PREFACE TO THE DOVER EDITION PREFACE 1. STRUCTURE AND SYMMETRY 1-1 Introduction 1-2 Bonding Geometrics in Carbon Compounds 1-3 Bonding Orbitals in Carbon Compounds 1-4 Reflection Symmetry-Point Groups 1-5 Molecular Deformations and Strain Energies 1-6 Molecular Models 1-7 Exercises 2. STEREOISOMERISM 2-1 Classification of Structural Isomerism-Enantiomeric and Diastereomeric Relationships 2-2 Optical Activity 2-3 Diastereomers and Racemic Forms 2-4 Torsional Stereoisomerism 2-5 Stereoisomerism Resulting from Asymmetric Atoms-Designation of Configuration at Asymmetric Atoms 2-6 Torsional Stereoisomerism in the Presence of Asymmetric Atoms 2-7 Macromolecules 2-8 Topological Isomerism 2-9 Exercises 3. SEPARATION AND CONFIGURATION OF STEREOISOMERS 3-1 Separation of Enantiomers and Diastereomers 3-2 Optical Activation 3-3 Asymmetric Synthesis and Kinetic Resolution 3-4 Absolute Configuration 3-5 Configurational Correlations by Chemical Methods 3-6 Configurational Correlations by Physical Methods 3-7 Exercises ANSWERS TO EXERCISES BIBLIOGRAPHY INDEX

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