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Mechanistic Bioinorganic Chemistry


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Understanding the Mechanisms in Bioinorganic Chemistry ; Insights into the Role of Nickel in Hydrogenase ; Modeling Phenoxyl Radical Metalloenzyme Active Sites ; Reactivity Models for Dinuclear Iron Metalloenzymes: Oxygen Atom Transfer Catalysis and Dioxygen Activation ; Electronic Structures of Active Sites in Copper Proteins and Their Contributions to Reactivity ; Biomimetic Copper-Dioxygen Chemistry: Reversible O[2-Binding and Mechanistic Insights into Cu(I)/O[2-Mediated Arene Hydroxylation and Amide Hydrolysis ; Synthetic Modeling of the Interactions of Nitrogen Oxides with Copper Proteins: Copper Nitrosyl Complexes Relevant to Putative Denitrification Intermediates ; Structural Characterization of Manganese Redox Enzymes: Results from X-Ray Absorption Spectroscopy ; Structure and Function of Manganese in Photosystem II ; Reactivity and Mechanism of Manganese Enzymes: A Modeling Approach ; Application of NMR Spectroscopy to Studies of Aqueous Coordination Chemistry of Vanadium(V) Complexes ; Modeling Vanadium Bromoperoxidase: Oxidation of Halides by Peroxovanadium(V) Complexes ; Magnetic Circular Dichroism Spectroscopy as a Probe of the Active Site Structures of Iron Chlorin- and Formylporphyrin-Containing Green Heme Proteins ; Mechanistic Aspects of the Chemistry of Iron N-Alkyl Porphyrins ; Mechanisms of DNA Cleavage by High-Valent Metal Complexes ; Metal Ion Macrocyclic Complexes as Artificial Ribonucleases ; Metallointercalators as Probes of the DNA pi-way ; Donor-Acceptor Electronic Coupling in Rutheniuim-Modified Heme Proteins


"The volume prepared by H. Holden Throp [sic] and Vincent L. Pecoraro gathers the papers presented at the 205th International Meeting of ACS (Division of Inorganic Chemistry). Viewed globally, it represents a valuable synthesis of the present state-of art-and [sic] knowledge on the interferences of inorganic chemistry with the living matter. . . . The volume is structured into 18 chapters, each of them an independent study of a high level of scientific performance. It is of interest to specialists in enzymology, coordinative chemistry, spectroscopy and molecular biology. Modelling of some metabolic processes involving metallic ions, as well, study of the formation of macrocyclic complexes during metabolic processes, and some applications of biomimetics constitute the main objective of the volume under review. . . . [R]ecommended . . . to all people aiming at developing highly performant scientific investigations."--Cellulose Chemistry and Technology

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