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Molecular Basis of Polymer Networks


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Table of Contents

I Theoretical Concepts.- A Naive Approach to the Physics of Polymer Networks: Remarks, Questions and Prospects.- The Baumgartner-Muthukumar Effect in Networks.- Statistical Mechanics of d-Dimensional Polymer Networks and Exact Results in Two Dimensions.- Polyelectrolyte Gels: Replica Theory.- Fluctuation-Induced Deformation Dependence of the Flory-Huggins Parameter.- Polymeric Fractal Blends.- II Small Angle Neutron Scattering.- Swelling and Deswelling of Polymer Networks Investigated by Different Types of SANS Experiments: Comments About the Structure.- SANS Probing of Statics and Dynamics of Polymer Networks Under Deformation: Relation Between the Scatterings of Labeled Paths and Labeled Free Chains Dissolved in the Network.- Diffusional Processes in Polymer Networks as Studied by Neutron Spin Echo Spectroscopy.- III Microscopic Conformation and Properties.- Molecular Deformation, Segmental Orientation and Segmental Mobility in Amorphous Polymeric Networks.- Orientational Order Induced in Strained Polymer Networks as Revealed by 2H-NMR.- Effect of Polymer Density on the Orientational Interactions in PDMS Networks: A 2H NMR Study.- Local Orientation and Global Deformation of Network Chains in Strained Elastomeric Networks.- Tests of the Flory-Rehner Hypothesis: Comparison of the Elastic Free Energy Function for Crosslinked Rubber in the Dry and Swollen States.- Swelling of Lightly Cross-Linked Polymer Networks.- Synthesis and Properties of Polystyrene Model Micronetworks.- QELS and SANS Study of Poly(acrylic acid) Gels.- Network Deformation in Flow.- Thermoplastic Elastometers by Hydrogen Bonding.- Salt Effects on Gel-Forming Ionic Polysaccharides.- Investigations of the Complex Shear Modulus and the Optical Rotation in the System Gelatin-Water During the Thermoreversible Gelation Process.- IV Model Networks.- The Deformation of Entropic Rigid Rod Networks.- Segment Distribution for Terminally Attached Poly(ethylene oxide) Chains.- Computer Simulation of Model Polymer Networks.- Entropy Elastic Forces of Chain Molecules.- V Liquid Crystal Networks.- Structures and Phase Transition of Elastomer Liquid Crystals.- Liquid Crystalline Polymer Networks.- VI Star-Branched Polymers.- Small-Angle Neutron Scattering from Star-Branched Polymers.- Neutron Spin Echo Investigation on the Dynamics of Star Polymers.- Monte Carlo Simulation of Star Polymers.- On the Viscosity of a System of Star Molecules.- Index of Contributors.

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