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Organic Synthesis Workbook
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Table of Contents

Chapter 1. Mienfiensine. (Overman 2005) Key chemistry: Enantioselective Heck Reactions. Chapter 2. Myriaporone 4. (Taylor, 1998, 2004) Key Chemistry: Evans Aldol Reactions. Chapter 3. Ningalin D. (Boger 2005) Key Chemistry: Pyrrole Synthesis using a 1,2,4,5-Tetrazine 1,2-Diazine Pyrrole Strategy. Chapter 4. BIRT-377. (Barbas 2005) Key Chemistry: Organocatalysis Chapter 5. Vitamin E. (Tietze 2006) Key Chemistry: Palladium (II)- catalyzed Domino Wacker-Heck Reaction. Chapter 6. (+)-Cyanthiwigin U. (Phillips 2005, Palomo 2002). Key Chemistry: Alkene Metathesis. Chapter 7. XK-EPO. (Schering AG 2006) Key Chemistry: Macrolactonization. Chapter 8. (+)-Laurenine. (Boeckmann 2002) Key Chemistry: Enantioselective Reduction of Ketones. Chapter 9. Cylindramide. (Laschat 2005) Key Chemistry: Oxidation of Ketones to the Corresponding a,ss-unsaturated carbonyl compounds via the Silyl enol ether. Chapter 10. Peridinin. (Bruckner 2006) Key Chemistry: Formation of C=C double bonds. Chapter 11. Laulimalide. (Mulzer 2003) Key Chemistry: Asymmetric Epoxidation of Alkenes. Chapter 12. Cystothiazole B. (Panek 2004) Key Chemistry: Stereoselective Crotylation of Aldehydes with Chiral Crotyl Silanes. Chapter 13. (+)-Pentacycloanammoxic acid. (Corey 2006) Key Chemistry: Photochemical Cycloadditions. Chapter 14. (-)-Dactylolide (McLeod 2006). Key Chemistry: [3,3]-Sigmatropic Ireland-Claisen Rearrangement. Abbreviations. Index.

About the Author

Tom Kinzel started studying chemistry at the University of Goettingen, Germany, in October 1998. After staying in the Peoples Republic of China in 2001/2002 studying Chinese at the University of Nanjing and joining the working group of Prof. Henning at the Chinese Academy of Sciences in Shanghai, he returned to Goettingen and received his diploma in Chemistry in July 2004. He is now a doctoral researcher in Gottingen. His research deals with the elucidation of reaction mechanisms by both theoretical and experimental means. Felix Major started studying Chemistry at the University of Goettingen, Germany, in October 1998. After joining the group of Prof. Clayden at the University of Manchester for 3 months in 2002 he returnded to Goettingen and accomplished his diploma in September 2003 under the guidance of Prof. Tietze. He is now doing his doctoral research in the same group focusing on the synthesis and biological evaluation of prodrug analogues of the antibiotic CC-1065 for a selective treatment of cancer. Thomas Redert started studying chemistry at the University of Goettingen, Germany, in October 1999. After staying in the United Kingdom in 2002/2003 at the University of Newcastle upon Tyne and joining the group of Dr. J.G. Knight, he returned to Goettingen and received his diploma in chemistry in July 2004. He is currently a doctoral researcher at the University of Goettingen. His research deals with the application of Palladium-catalyzed dominocyclisations for the synthesis of natural product analagues. Florian Stecker received his diploma in organic chemistry from the University of Goettingen, Germany, in July 2004. He started studying chemistry in Goettingen in October 1999 and worked at the Universite Pierre et Marie Curie (Paris VI) under the direction of Prof. Max Malacria in 2002/2003. Shortly thereafter, he joined the group of Prof. Tietze (Goettingen) where he is currently a doctoral researcher. He is committed to the Palladium-catalyzed domino-Wacker-Heck reaction for the enantioselective synthesis of vitamin E and other closely related chromanes/chromenes. Julia Zinngrebe started studying chemistry at the University of Goettingen, Germany, in October 1998. After joinging the group of Prof. Clayden at the University of Manchester for 3 months in 2002 she returned to Goettingen and accomplished her diploma in September 2003 under the guidance of Prof. Tietze. She is now doing her doctoral research in the same group and works in the field of Palladium-catalyzed domino-reactions for the enantioselective synthesis of vitamin E.

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