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Polar Rearrangements

The general principles of polar rearrangements are brought together in this text, which deals with all the major rearrangements involving electron-deficient atoms or charged intermediates. Reactions involving migration to electron-deficient carbon, nitrogen, oxygen and sulphur, and sigmatropic rearrangements involving polar species, are thus treated in a coherent and consistent manner. Clear discussions of the reaction mechanisms are followed by examples of synthetic applications providing a concise yet comprehensive account of the nature of and importance of these processes.
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Table of Contents

Rearrangements involving migrations to electron deficient carbon; Rearrangements involving migrations to and from electron deficient nitrogen; Rearrangements involving migrations to and from electron deficient oxygen; Rearrangements involving electron deficient sulphur; Sigmatropic rearrangements involving polar species


'The book provides an excellent introduction to the mechanistic and synthetic topic of rearrangements ... the explanations are very clear and concise ... This is another excellent book in the series, which continues to impress me. I would recommend this book as essential reading to all undergraduates.' David Baker, Education in Chemistry, September 1993 'a highly specialised chemistry text-book ... intended for for students of organic chemistry at a fairly advanced level' Aslib Book Guide, Vol. 57, No. 8, August 1992

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