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Table of Contents

to Volume 1 and Instructions for the Use of this Book and its Indexes.- I. Organometallic Reagents, Solvents and Laboratory Equipment.- 1. Strongly Basic Reagents used in Organic Synthesis.- 2. Solvents and Some Reagents: Their Analysis, Purification and Storage.- 3. Laboratory Equipment and Some General Remarks Concerning Performance of the Procedures.- 4. Safety, Handling and Methods of Disposal.- 5. Experimental Procedures.- II Reactivity of Polar Organometallic Intermediates.- 1. Introduction.- 2. General Remarks About Reactivity.- 3. Alkylation Reactions.- 4. Acylation Reactions.- 5. Carboxylation.- 6. Additions to Carbonyl Compounds.- 7. Additions to Heterocumulenes.- 8. Reactions with Sulfenylating Reagents.- 9. Reactions with Elemental Sulfur, Selenium and Tellurium.- 10. Reactions with Sulfur Dichloride.- 11. Trimethylsilylation.- 12. Introduction of Chlorine, Bromine and Iodine.- 13. Protonation and Deuteration.- 14. Exchange Between Counter Ions.- III. Metallated Olefinic and Allenic Hydrocarbons.- 1. Deprotonation with Strongly Basic Reagents.- 2. Halogen-Lithium and Tin-Lithium Exchange.- 3. Direct Preparation from Halogen Compounds and Metal.- 4. Experimental Procedures.- IV. Metallation of Hetero-Substituted Unsaturated Systems.- 1. Introduction.- 2. ?-Metallation of 1-Alkenyl Ethers, -Thioethers and Related Systems.- 3. ?-Metallation of 1.3-Dienyl Ethers and —Thioethers.- 4. ?-Metallated Haloalkenes.- 5. ?-Metallated Allenic Ethers, —Thioethers and —Amines.- 6. Metallated 1,2,3-Butatrienyl Ethers, —Sulfides and -Amines.- 7. Addendum: Metallation of N,N-Dialkylformamides and-Thioformamides.- 8. Experimental Procedures.- V. Metallated Hetero-Aromatic Compounds.- 1. Introduction.- 2. Metallated Furans, Pyrroles, Thiophenes, Selenophenes andTellurophenes.- 3. Metallated Pyridines.- 4. Metallated Hetero-Aromatics with more than one Hetero Atom.- 5. Experimental Procedures.- VI. Metallated Aromatic Compounds.- 1. Metallated Aromatic Hydrocarbons.- 2. Metallated Hetero-Substituted Arenes.- 3. Experimental Procedures.- 1. Generation of Polar Organometallic Intermediate by Deprotonation with Strongly Basic Reagents.- 2. Metallation-Functionalization Index.- 3. Index of Reaction Types.- References.